First, let's get the tedious part of the process out of the way. For the most part, I hand paint each little particle so they fall exactly where I want them to go. I use Photoshop's default brush with zero percent hardness and click around constantly tapping the bracket buttons (right next to the "P" key - they are quick commands for enlarging and shrinking your brush size). I try to make sure there's a somewhat natural flow to them and not to have all of them too perfectly spaced out. There is definitely an art to particle placement.
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